UAM_Biblioteca

View Item 

Show simple item record

Dissociation dynamics of the diamondoid adamantane upon photoionization by XUV femtosecond pulses

dc.contributor.authorMaclot, Sylvain
dc.contributor.authorLahl, Jan
dc.contributor.authorPeschel, Jasper
dc.contributor.authorWikmark, Hampus
dc.contributor.authorRudawski, Piotr
dc.contributor.authorBrunner, Fabian
dc.contributor.authorCoudert-Alteirac, Hélène
dc.contributor.authorIndrajith, Suvasthika
dc.contributor.authorHuber, Bernd A.
dc.contributor.authorDíaz-Tendero Victoria, Sergio 
dc.contributor.authorAguirre, Néstor F.
dc.contributor.authorRousseau, Patrick
dc.contributor.authorJohnsson, Per
dc.contributor.otherUAM. Departamento de Física de la Materia Condensadaes
dc.contributor.otherUAM. Departamento de Químicaes
dc.date.accessioned2020-05-25T11:20:39Z
dc.date.available2020-05-25T11:20:39Z
dc.date.issued2020-12-01
dc.identifier.citationScientific Reports 10 (2020): 2884en_US
dc.identifier.issn2045-2322
dc.identifier.urihttp://hdl.handle.net/10486/691104
dc.description.abstractThis work presents a photodissociation study of the diamondoid adamantane using extreme ultraviolet femtosecond pulses. The fragmentation dynamics of the dication is unraveled by the use of advanced ion and electron spectroscopy giving access to the dissociation channels as well as their energetics. To get insight into the fragmentation dynamics, we use a theoretical approach combining potential energy surface determination, statistical fragmentation methods and molecular dynamics simulations. We demonstrate that the dissociation dynamics of adamantane dications takes place in a two-step process: barrierless cage opening followed by Coulomb repulsion-driven fragmentationen_US
dc.description.sponsorshipThis research was supported by the Swedish Research Council, the Swedish Foundation for Strategic Research and the Crafoord Foundation. This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie Grant Agreement No. 641789 MEDEA and under grant agreement no 654148 Laserlab-Europe. The research was conducted in the framework of the International Associated Laboratory (LIA) Fragmentation DYNAmics of complex MOlecular systems - DYNAMO, funded by the Centre National de la Recherche Scientifique (CNRS). The authors acknowledge the generous allocation of computer time at the Centro de Computación Científica at the Universidad Autónoma de Madrid (CCC-UAM). This work was partially supported by the project CTQ2016-76061-P of the Spanish Ministerio de Economía y Competitividad (MINECO). Financial support from the MINECO through the "María de Maeztu” Program for Units of Excellence in R&D (MDM-2014-0377) is also acknowledgeden_US
dc.format.extent12 pag.en_US
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherNature Publishing Groupen_US
dc.relation.ispartofScientific Reportsen_US
dc.rights© 2020, The Author(s)en_US
dc.subject.otherDiamondoid adamantaneen_US
dc.subject.otherUltraviolet femtosecond pulsesen_US
dc.subject.otherCoulomb repulsion-driven fragmentationen_US
dc.titleDissociation dynamics of the diamondoid adamantane upon photoionization by XUV femtosecond pulsesen_US
dc.typearticleen
dc.subject.ecienciaFísicaes
dc.subject.ecienciaQuímicaes
dc.relation.publisherversionhttps://doi.org/10.1038/s41598-020-59649-1
dc.identifier.doi10.1038/s41598-020-59649-1
dc.identifier.publicationfirstpage2884-1
dc.identifier.publicationissue10
dc.identifier.publicationlastpage2884-12
dc.identifier.publicationvolume2020
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/641789/EU//MEDEAen_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/654148/EU//Laserlab-Europeen_US
dc.relation.projectIDGobierno de España. CTQ2016-76061-Pes_ES
dc.relation.projectIDGobierno de España. MDM-2014-0377es_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.rights.ccReconocimientoes_ES
dc.rights.accessRightsopenAccessen
dc.authorUAMDíaz-Tendero Victoria, Sergio (262857)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)
dc.institutoUAMInstituto de Investigación Avanzada en Ciencias Químicas (IAdChem)


Files in this item

Thumbnail
Name:
dissociation_diaz-tendero_sr_2 ...
Size:
2.288Mb
Format:
PDF

This item appears in the following Collection(s)

Show simple item record