dc.contributor.author | Schierl, Christoph | |
dc.contributor.author | Pardo, Virtudes | |
dc.contributor.author | Bottari, Giovanni | |
dc.contributor.author | Guldi, Dirk M. | |
dc.contributor.author | Torres Cebada, Tomás | |
dc.contributor.other | UAM. Departamento de Química Orgánica | es_ES |
dc.date.accessioned | 2021-11-04T14:48:18Z | |
dc.date.available | 2021-11-04T14:48:18Z | |
dc.date.issued | 2020-01-06 | |
dc.identifier.citation | ECS Journal of solid state and technology 9.5 (2020): 051011 | en_US |
dc.identifier.issn | 2162-8769 (print) | en_US |
dc.identifier.issn | 2162-8777 (online) | en_US |
dc.identifier.uri | http://hdl.handle.net/10486/698620 | |
dc.description.abstract | A rod-like cyclopenta[hi]aceanthrylene (CPA) derivative bearing three dodecyloxy chains at each of its two terminal positions was prepared. Spectroscopic (i.e., steady-state absorption and fluorescence) and electrochemical studies carried out with this polycyclic aromatic hydrocarbon (PAH) derivative showed an intense absorption through the entire UV-vis spectral range, weak fluorescence, small HOMO-LUMO gap, and excellent electron accepting capability. Transient absorption spectroscopy (TAS) revealed the formation of singlet and triplet excited states; the latter was, however, only observed in the presence of a triplet sensitizer. The exfoliation capability of this lipophilic CPA towards single-walled carbon nanotubes (SWCNTs) in THF was also investigated. On one hand, transmission electron microscopy (TEM) pointed to an efficient debundling of SWCNTs by the CPA derivative by means of non-covalent interactions. On the other hand, important differences in the ground and excited state features of the uncomplexed and SWCNT-complexed CPA were revealed by Raman and TAS | en_US |
dc.description.sponsorship | Financial support from the “Solar Energy goes Hybrid” Initiative of the Bavarian Ministry for Science, Culture and Education (SolTech), Comunidad de Madrid (FOTOCARBON), and Spanish MICINN (CTQ2017-85393-P) is acknowledged | en_US |
dc.format.extent | 6 pag. | es_ES |
dc.format.mimetype | application/pdf | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Electrochemical Society | en_US |
dc.relation.ispartof | ECS Journal of Solid State Science and Technology | en_US |
dc.rights | © 2020 The Author(s) | en_US |
dc.subject.other | (CPA) | es_ES |
dc.subject.other | Absorption spectroscopy | en_US |
dc.subject.other | Fluorescence | en_US |
dc.subject.other | Nanotubes | en_US |
dc.title | Cyclopenta[hi]aceanthrylene decorated with multiple and long alkoxy chains: physicochemical properties and single-walled carbon nanotubes exfoliation capability | en_US |
dc.type | article | en_US |
dc.subject.eciencia | Química | es_ES |
dc.relation.publisherversion | https:/doi.orgi/10.1149/2162-8777/ab9a5a | es_ES |
dc.identifier.doi | 10.1149/2162-8777/ab9a5a | es_ES |
dc.identifier.publicationfirstpage | 051011-1 | es_ES |
dc.identifier.publicationissue | 5 | es_ES |
dc.identifier.publicationlastpage | 051011-6 | es_ES |
dc.identifier.publicationvolume | 9 | es_ES |
dc.relation.projectID | Gobierno de España. CTQ2017-85393-P | es_ES |
dc.relation.projectID | Comunidad de Madrid. S2013/MIT-2841/FOTOCARBON | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.rights.cc | Reconocimiento | es_ES |
dc.rights.accessRights | openAccess | es_ES |
dc.authorUAM | Bottari, Giovanni (261162) | |
dc.authorUAM | Torres Cebada, Tomás (259468) | |
dc.facultadUAM | Facultad de Ciencias | |