UAM_Biblioteca

View Item 

Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis

Author
Guerrero-Corella, Andrea; Fraile Carrasco, Albertountranslated; Alemán Lara, José Juliánuntranslated
Entity
UAM. Departamento de Química Orgánica
Publisher
American Chemical Society
Date
2022-02-03
Citation
ACS Org. Inorg. Au 2 (2022): 197-204
ISSN
2694-247X (online)
Funded by
Financial support was provided by the European Research Council (ERC-CoG, Contract No. 647550, ERC-PoC, Contract No. 861930), the Spanish Government (RTI2018- 095038-B-I00), “Comunidad de Madrid”, and European Structural Funds (S2018/NMT-4367) and proyectos sinérgicos I+D (Y2020/NMT-6469). A.G.-C. acknowledges a predoctoral FPI fellowship
Project
Gobierno de España. RTI2018-095038-B-I00
Editor's Version
https://doi.org/10.1021/acsorginorgau.1c00053
Subjects
Intramolecular activation,; Hydrogen bonding; Organocatalysis; Metal catalysis; Bifunctional catalysis; Asymmetric synthesis; Química
URI
http://hdl.handle.net/10486/702717
Rights
© 2022 The Authors

Abstract

The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes
Show full item record

Files in this item

Thumbnail
Size
2.339Mb
Format
PDF
Description
Artículo

Google™ Scholar:Guerrero-Corella, Andrea - Fraile Carrasco, Alberto - Alemán Lara, José Julián

This item appears in the following Collection(s)