Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
Entidad
UAM. Departamento de Química OrgánicaEditor
American Chemical SocietyFecha de edición
2022-02-03Cita
ACS Org. Inorg. Au 2 (2022): 197-204ISSN
2694-247X (online)Financiado por
Financial support was provided by the European Research Council (ERC-CoG, Contract No. 647550, ERC-PoC, Contract No. 861930), the Spanish Government (RTI2018- 095038-B-I00), “Comunidad de Madrid”, and European Structural Funds (S2018/NMT-4367) and proyectos sinérgicos I+D (Y2020/NMT-6469). A.G.-C. acknowledges a predoctoral FPI fellowshipProyecto
Gobierno de España. RTI2018-095038-B-I00Versión del editor
https://doi.org/10.1021/acsorginorgau.1c00053Materias
Intramolecular activation,; Hydrogen bonding; Organocatalysis; Metal catalysis; Bifunctional catalysis; Asymmetric synthesis; QuímicaDerechos
© 2022 The AuthorsResumen
The activation of molecules through intramolecular hydrogen-bond
formation to promote chemical reactions appears as a suitable strategy in organic
synthesis, especially for the preparation of chiral compounds under metal and
organocatalytic conditions. The use of this interaction has enabled reactivity enhancement
of reagents, as well as stabilization of the chemical species and enantiocontrol of the
processes
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Google Scholar:Guerrero-Corella, Andrea
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Fraile Carrasco, Alberto
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Alemán Lara, José Julián
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