UAM_Biblioteca | Unified search engine | Scientific Production Portal | UAM Research Data Repository
Universidad Autónoma de Madrid
Biblos-e Archivo
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram
    • español
    • English
  • English 
    • español
    • English
  • Log in
JavaScript is disabled for your browser. Some features of this site may not work without it.

Search Biblos-e Archivo

Advanced Search

Browse

All of Biblos-e ArchivoCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsFacultiesThis CollectionBy Issue DateAuthorsTitlesSubjectsFaculties

My Account

Log inRegister

Statistics

View Usage Statistics

Help

Information about Biblos-e ArchivoI want to submit my workI want to submit my doctoral thesisFrequently Asked QuestionsCopyrightsFinancial Agencies and OA policy

UAM_Biblioteca

View Item 
  •   Biblos-e Archivo
  • 1 - Producción científica en acceso abierto de la UAM
  • Producción científica en acceso abierto de la UAM
  • View Item
  •   Biblos-e Archivo
  • 1 - Producción científica en acceso abierto de la UAM
  • Producción científica en acceso abierto de la UAM
  • View Item

Theoretical Challenges in Polaritonic Chemistry

Author
Fregoni, Jacopountranslated; Garcia-Vidal, Francisco J.; Feist, Johannes
Entity
UAM. Departamento de Física Teórica de la Materia Condensada
Publisher
American Chemical Society
Date
2022-02-15
Citation
ACS Photonics 9.4 (2022): 1096-1107
 
 
 
ISSN
2330-4022 (online)
Funded by
This work has been funded by the European Research Council through Grant ERC-2016-StG-714870 and by the Spanish Ministry for Science, Innovation, and Universities − Agencia Estatal de Investigaciòn through Grants RTI2018-099737-BI00, PCI2018-093145 (through the QuantERA program of the European Commission), and CEX2018-000805-M (through the Marìa de Maeztu Program for Units of Excellence in R&D). We also acknowledge financial support from the Proyecto Sinèrgico CAM 2020 Y2020/TCS-6545 (Nano- QuCo-CM)
Project
Gobierno de España. RTI2018-099737-BI00; Gobierno de España. PCI2018-093145
Editor's Version
https://doi.org/10.1021/acsphotonics.1c01749
Subjects
Molecular polaritons; Strong coupling; Photochemistry; Nanoplasmonics; Resonant cavities; Cavity-QED; Física
URI
http://hdl.handle.net/10486/702763
Rights
© 2022 The Authors

Abstract

Polaritonic chemistry exploits strong light−matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both the confinement of the electromagnetic field and the number of molecules that are involved in the process. While in wavelengthscale optical cavities the light−matter interaction is ruled by collective effects, plasmonic subwavelength nanocavities allow even single molecules to reach strong coupling. Due to these very distinct situations, a multiscale theoretical toolbox is then required to explore the rich phenomenology of polaritonic chemistry. Within this framework, each component of the system (molecules and electromagnetic modes) needs to be treated in sufficient detail to obtain reliable results. Starting from the very general aspects of light−molecule interactions in typical experimental setups, we underline the basic concepts that should be taken into account when operating in this new area of research. Building on these considerations, we then provide a map of the theoretical tools already available to tackle chemical applications of molecular polaritons at different scales. Throughout the discussion, we draw attention to both the successes and the challenges still ahead in the theoretical description of polaritonic chemistry
Show full item record

Files in this item

Thumbnail
Name
theoretical_fregoni_acs_photonics_2022.pdf
Size
2.456Mb
Format
PDF
Description
Artículo

Refworks Export

Delicious Save this on Delicious

Google™ Scholar:Fregoni, Jacopo - Garcia-Vidal, Francisco J. - Feist, Johannes

This item appears in the following Collection(s)

  • Producción científica en acceso abierto de la UAM [14739]

Related items

Showing items related by title, author, creator and subject.

  • Many-molecule reaction triggered by a single photon in polaritonic chemistry 

    Galego, Javier; Garcia-Vidal, Francisco J.; Feist, Johannes
    2017-09-27
  • Polaritonic Chemistry with organic molecules 

    Feist, Johannes; Galego, Javier; Garcia-Vidal, Francisco J.
    2018-01-17
  • Polaritonic molecular clock for all-optical ultrafast imaging of wavepacket dynamics without probe pulses 

    Silva, R. E.F.; Pino, Javier del; García-Vidal, Francisco J.; Feist, Johannes
    2020-03-17
All the documents from Biblos-e Archivo are protected by copyrights. Some rights reserved.
Universidad Autónoma de Madrid. Biblioteca
Contact Us | Send Feedback
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram
 

 

All the documents from Biblos-e Archivo are protected by copyrights. Some rights reserved.
Universidad Autónoma de Madrid. Biblioteca
Contact Us | Send Feedback
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram