Phenanthroimidazole as molecularly engineered switch for efficient and highly long-lived light-emitting electrochemical cell
EntityUAM. Departamento de Química Inorgánica
10.1038/s41598-023-29527-7Scientific Reports 13.1 (2023): 2287
SubjectsLigands; Organic Light-Emitting Diodes; 2-Phenylpyridine; Química
Rights© The Author(s) 2023
Esta obra está bajo una Licencia Creative Commons Atribución 4.0 Internacional.
Light-emitting electrochemical cells (LECs) based on Ir(III) complexes owing to the superior advantages exhibit high potential for display and lighting applications. Herein, a series of Ir(III) complexes based on phenanthroimidazole (PI) as an ancillary ligand were synthesized to achieve efficient and highly stable yellow-to-orange LEC devices with fast response. These complexes exhibit appropriate electrochemical stability and significant suppression of concentration quenching in the thin films compared to the archetype complex. The fabricated LECs showed remarkably long device lifetimes over 1400 and 2100 h and external quantum efficiency of 2 and 3% for yellow and orange-LECs, respectively. The obtained t1/2 for yellow LEC is much higher than archetype [Ir(ppy)2(phen)]+ and their phenanthroline-based analogues reported so far. The incorporation of an ionic tethered functional group on PI, improved the mobility of the emissive layer and reduced the device turn-on time by 75–88%. This study shows a facile functionalization and characterization of the PI ligand as well as its potential application in optoelectronic devices (OLED)
Google Scholar:Nemati Bideh, Babak - Moghadam, Majid - Sousaraei, Ahmad - Shahpoori Arani, Behnoosh
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