Porous aromatic frameworks containing binaphthyl-dihydroazepine units (cBAPAFs) as catalytic supports for asymmetric reactions
Entity
UAM. Departamento de Química InorgánicaPublisher
ElsevierDate
2022-09-01Citation
10.1016/j.jcat.2022.06.034
Journal of Catalysis 413 (2022): 434 - 442
ISSN
0021-9517 (print); 1090-2694 (online)DOI
10.1016/j.jcat.2022.06.034Funded by
Authors acknowledge to Grants PID2020-112590GB-C22 funded by MCIN/AEI/10.13039/501100011033 and by ‘‘ERDF A way of making Europe”. A.V.G. thanks Ministerio de Universidades for FPU17/03463Project
Gobierno de España. PID2020-112590GB-C22Editor's Version
https://doi.org/10.1016/j.jcat.2022.06.034Subjects
Aromatization; Enantioselectivity; Metal Complexes; Organocatalyst; Styrene; QuímicaRights
© 2022 The AuthorsAbstract
We present the successfully synthesis of a series of chiral polymeric aromatic frameworks containing novel enantiopure atropoisomeric 1,1′-binaphthyl-dihydroazepine-based compounds as structural building units named cBAPAFs. Three porous materials with amino, pyridinic and amino-alcohol functionalities were successfully obtained from dibrominated monomers by Suzuki-Miyaura couplings. New porous materials present surface areas up to 619 m2 g−1 determined by Brunauer–Emmett–Teller (BET), and high thermal stability. The use of nitrogen-based structural units provides useful functional groups to allow a robust binding site for metal complexes. Thus, after post-synthetic metalation with Cu(OAc)2, these materials have been applied as efficient heterogenized catalysts for the nitroaldol (Henry) reaction and a multicomponent reaction, affording chiral products with comparable enantioselectivity to that of the homogeneous system. The materials were also tested as organocatalysts for the asymmetric addition of diethylzinc to benzaldehyde and the reaction between nitro-styrene and nitroethane. These cBAPAFs could be recycled for the asymmetric nitroaldol reaction for at least 5 cycles without a significant loss in its catalytic efficiency
Files in this item
Google Scholar:Valverde González, Antonio
-
Fernández-Seriñan, Pilar
-
Matarín, Ángela
-
Arnanz Lara, Avelina
-
Sánchez Alonso, Félix
-
Iglesias Fernández, Marta
This item appears in the following Collection(s)
Related items
Showing items related by title, author, creator and subject.
-
Genetic landscape of 6089 inherited retinal dystrophies affected cases in Spain and their therapeutic and extended epidemiological implications
Perea-Romero, Irene; Gordo, Gema; Iancu, Ionut F.; Del Pozo-Valero, Marta; Almoguera, Berta; Blanco-Kelly, Fiona; Carreño, Ester; Jimenez-Rolando, Belen; Lopez-Rodriguez, Rosario; Lorda-Sanchez, Isabel; Martin-Merida, Inmaculada; Pérez de Ayala, Lucia; Riveiro-Alvarez, Rosa; Rodriguez-Pinilla, Elvira; Tahsin-Swafiri, Saoud; Trujillo-Tiebas, Maria J.; Bustamante-Aragones, Ana; Cardero-Merlo, Rocio; Fernandez-Sanchez, Ruth; Gallego-Merlo, Jesus; Garcia-Vara, Ines; Gimenez-Pardo, Ascension; Horcajada-Burgos, Laura; Infantes-Barbero, Fernando; Lantero, Esther; Lopez-Martinez, Miguel A.; Martinez-Ramas, Andrea; Ondo, Lorena; Rodriguez de Alba, Marta; Sanchez-Jimeno, Carolina; Velez-Monsalve, Camilo; Villaverde, Cristina; Zurita, Olga; Aguilera-Garcia, Domingo; Aguirre-Lamban, Jana; Arteche, Ana; Cantalapiedra, Diego; Fernandez-San Jose, Patricia; Galbis-Martinez, Liliana; Garcia-Hoyos, Maria; Lombardia, Carlos; Lopez-Molina, Maria I.; Perez-Carro, Raquel; Da Silva, Luciana R.J.; Ramos, Carmen; Sanchez-Alcudia, Rocio; Sanchez-Navarro, Iker; Tatu, Sorina D.; Vallespin, Elena; Aller, Elena; Bernal, Sara; Gamundi, Maria J.; Garcia-Garcia, Gema; Hernan, Inmaculada; Jaijo, Teresa; Antiñolo, Guillermo; Baiget, Montserrat; Carballo, Miguel; Millan, Jose M.; Valverde, Diana; Allikmets, Rando; Banfi, Sandro; Cremers, Frans P.M.; Collin, Rob W.J.; De Baere, Elfride; Hakonarson, Hakon; Kohl, Susanne; Rivolta, Carlo; Sharon, Dror; Alonso-Cerezo, Maria C.; Ballesta-Martinez, Maria J.; Beltran, Sergi; Benito Lopez, Carmen; Català-Mora, Jaume; Catalli, Claudio; Cotarelo-Perez, Carmen; Fernandez-Burriel, Miguel; Fontalba-Romero, Ana; Galán-Gómez, Enrique; Garcia-Barcina, Maria; Garcia-Cruz, Loida M.; Gener, Blanca; Gil-Fournier, Belen; Govea, Nancy; Guillen-Navarro, Encarna; Hernando Acero, Ines; Irigoyen, Cristina; Izquierdo-Álvarez, Silvia; Llano-Rivas, Isabel; López-Ariztegui, Maria A.; Lopez-Gonzalez, Vanesa; Lopez-Grondona, Fermina; Martorell, Loreto; Mendez-Perez, Pilar; Moreno-Igoa, Maria; Oancea-Ionescu, Raluca; Palau-Martinez, Francesc; Perez de Nanclares, Guiomar; Ramos-Fuentes, Feliciano J.; Rodriguez-Lopez, Raquel; Ayuso García, María del Carmen Tomasa
2021-12-01 -
A cluster-randomised clinical trial comparing two cardiovascular health education strategies in a child population: The Savinghearts project
Sánchez-Gómez, Luis María; Fernández Luque, María Jesús; Ruiz Díaz, Lourdes; Sánchez-Alcalde, Rosa; Sierra-García, Belén; Mayayo-Vicente, Soledad; Ruiz-López, Marta; Loeches-Belinchón, Pilar; López-Gónzález, Javier; González-Gamarra, Amelia; Gallego Arenas, Angela; Cubillo-Serna, Ana; Gil-Juberias, Gema; Pérez-Cayuela, Pilar; Arana Cañedo-Arguelles, Celina; García Pascual, Julia Natividad; Ruiz-Chércoles, Esther; Suárez Fernández, M. Carmen; García-Polo, Iluminada; Abad Pérez, Daniel; Ballesteros-Arribas, Juan Manuel; Izquierdo Martínez, Maravillas; Salvador-Alcaide, Elena; Arribas-Vela, Ana B.; Alonso-Pérez, Juan M.; Veja-Piris, Lorena; Rodríguez-Salvanés, Francisco J.; Novella Arribas, Blanca
2012-11-27 -
Acceptability and feasibility of a virtual community of practice to primary care professionals regarding patient empowerment: A qualitative pilot study
Bermejo-Caja, Carlos Jesús; Koatz, Débora; Orrego, Carola; Perestelo-Pérez, Lilisbeth; González-González, Ana Isabel; Ballester, Marta; Pacheco-Huergo, Valeria; Del Rey-Granado, Yolanda; Muñoz-Balsa, Marcos; Ramírez-Puerta, Ana Belén; Canellas-Criado, Yolanda; Pérez-Rivas, Francisco Javier; Toledo-Chávarri, Ana; Martínez Marcos, María Mercedes; Alejo-Díaz-Zorita, Concepción; Barbero-Macías, Cynthia A.; Borrell-Punzón, Fernando; Bueno-Rodriguez, Beatriz; Colmena-Martin, Begoña; Del Valle-De Joz, Isabel; Gamboa-Puñal, Juan Carlos; García-Valverde, Concepción; Gómez-Garzón, Luis Miguel; Gómez-López, Arturo; Hernaz-Guijo, Alejandro; Herrera-León, Walter Nery; Iniesta-González, Irene; Leza-Leza, Margarita; Melchor-Canelo, María Aranzazu; Muñoz-Quirós-Aliaga, Sagrario; Oria-Fernández, Ángela; Pertierra-Galindo, Nuria; Prieto-Barbosa, M. Dolores; Robledo-Vázquez, Milagros; Ruiz-López, Marta; Sánchez-Cruz, M. Carmen; Sánchez-De-Eusebio, M. Ángeles; Seijas-Martínez-Echevarría, M. Jose; Tovar-García, Carmen Paola; Vicente-Diez, Jose Ignacio; Villanueva-Sanz, Cristina
2019-06-20