Triflyl-assisted reductive Pd-catalyzed Tsuji-Trost type reaction
Entity
UAM. Departamento de Química OrgánicaPublisher
Royal Society of ChemistryDate
2020-04-21Citation
10.1039/d0cc02146f
Chemical Communications 56.45 (2020): 6070-6073
ISSN
1359-7345 (print); 1364-548X (online)DOI
10.1039/d0cc02146fFunded by
This work was supported in part by AEI (MICIU) and FEDER (Projects PGC2018-095025-B-I00 and CTQ2016-79826-R). M. T. Q. thanks MICIU for a Juan de la Cierva contract. C. L. M. thanks MICIU and UCM for a postdoctoral contract. We thank the Centro de Computación Científica-UAM for computational timeProject
Gobierno de España. PGC2018-095025-B-I00; Gobierno de España. CTQ2016-79826-REditor's Version
https://doi.org/10.1039/d0cc02146fSubjects
Allylation; Allyl Alcohol; Catalysis; QuímicaRights
© 2020 The Royal Society of ChemistryAbstract
New (triflyl)cyclobutenes have been prepared by palladium-catalyzed hydrodetriflylation reaction using water and deuterium oxide as convenient hydrogen and deuterium sources. In addition, an investigation of the possible mechanism for this Tsuji-Trost type reaction of bis(triflyl)cyclobutenes has been facilitated by labelling studies and density functional theory (DFT) calculations
Files in this item
Google Scholar:Lázaro-Milla, Carlos
-
Quirós, M. Teresa
-
Cárdenas Morales, Diego Jesús
-
Almendros, Pedro
This item appears in the following Collection(s)
Related items
Showing items related by title, author, creator and subject.