Double catalytic activity unveiled: Synthesis, characterization, and catalytic applications of iridium complexes in transfer hydrogenation and photomediated transformations
Entity
UAM. Departamento de Química Inorgánica; UAM. Departamento de Química OrgánicaPublisher
American Chemical SocietyDate
2024-04-11Citation
10.1021/acscatal.4c00673
ACS Catalysis 14. (2024): 6413–6422
ISSN
2155-5435 (online)DOI
10.1021/acscatal.4c00673Funded by
PID2021-122299NB-100, TED2021-130470B-100, TED2021-129999B-C32, S2018/NMT-4367, Y2020/NMT6469Project
Gobierno de España. PID2021-122299NB-100; Gobierno de España. TED2021-130470B-100; Gobierno de España. TED2021-129999B-C32; Comunidad de Madrid. S2018/NMT-4367/FotoArt-CM; Comunidad de Madrid. Y2020/NMT-6469/FOTOSURF-CMEditor's Version
https://doi.org/10.1021/acscatal.4c00673Subjects
Catalysis; Iridium; Photocatalysis; Tandem Catalysis; Transfer Hydrogenation; QuímicaRights
© 2024 The AuthorsAbstract
Iridium complexes have been demonstrated to be highly active catalysts for a wide variety of transformations. Their unique photophysical and photochemical properties render them as one of the most established photocatalysts. Moreover, iridium complexes are widely acknowledged for their efficiency in transfer hydrogenation reactions. However, the development of iridium complexes able to promote both traditional organometallic catalysis and photocatalysis is scarce. Thus, the design of iridium-based catalysts is still an active area of research. In this context, we targeted the synthesis of a family of Ir-Cp* systems to explore their (photo)catalytic applications. Here, we describe the synthesis, structural characterization, and photophysical properties of iridium complexes of formula [IrCp*Cl(N^O)]. These complexes have been applied with a double catalytic function, in transfer hydrogenation for carbonyl reduction and in different photomediated transformations
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Google Scholar:Blanco Cabello, Laura
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Uroz Santos, Andrea
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Gutiérrez Contreras, Kevin Mauricio
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Cabrera Herranz, Silvia
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Collado Martínez, Alba
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Alemán Lara, José Julián
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