A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence
Entity
UAM. Departamento de Química InorgánicaPublisher
Royal Society of ChemistryDate
2016-01-01Citation
10.1039/C6TC02401G
Journal of Materials Chemistry C 4.36 (2016): 8545-8551
ISSN
2050-7526 (print); 2050-7534 (online)DOI
10.1039/C6TC02401GFunded by
This work was supported by MICINN (MAT2013-46753-C2-1-P and CTQ2013-48635-C2-1-P) and Generalitat Valenciana (projects PrometeoII/2014/076 and ISIC)Project
Gobierno de España. MAT2013-46753-C2-1-P; Gobierno de España. CTQ2013-48635-C2-1-PEditor's Version
https://doi.org/10.1039/C6TC02401GSubjects
Coordination reactions; Crystalline materials; Luminescence; Silver; Thin films; Film preparation; QuímicaRights
© 2016 The Royal Society of Chemistry.Abstract
The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)]n (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.
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Google Scholar:Troyano, Javier
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Castillo, Óscar
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Amo Ochoa, María Pilar
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Fernández-Moreira, Vanesa
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Gómez-García, Carlos J.
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Zamora Abanades, Félix Juan
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Delgado Gil, Salomé
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