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Enantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approach

dc.contributor.authorGuisán-Ceinos, M.
dc.contributor.authorParra Alfambra, Ana María 
dc.contributor.authorMartín-Heras, Víctor
dc.contributor.authorTortosa Manzanares, Mariola 
dc.contributor.otherUAM. Departamento de Química Orgánicaes_ES
dc.date.accessioned2016-06-16T12:55:39Z
dc.date.available2016-06-16T12:55:39Z
dc.date.issued2016-05-09
dc.identifier.citationAngewandte Chemie 128. 24 (2016): 7083–7086es_ES
dc.identifier.issn1521-3757es_ES
dc.identifier.urihttp://hdl.handle.net/10486/671466
dc.descriptionThis is the peer reviewed version of the following article: Guisán-Ceinos, M., Parra, A., Martín-Heras, V. and Tortosa, M. (2016), Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach. Angew. Chem., which has been published in final form at http://dx.doi.org/10.1002/ange.201601976. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.es_ES
dc.description.abstractIn this report, the first catalytic enantioselective synthesis of cyclobutylboronates, using a chiral copper(I) complex, is disclosed. A broad variety of cyclobutanes have been prepared with consistently high levels of diastereo- and enantiocontrol. Moreover, this method constitutes the first report of an enantioselective desymmetrization of meso-cyclobutenes to prepare chiral cyclobutaneses_ES
dc.description.sponsorshipWe thank the European Research Council (ERC-337776) and MINECO (CTQ2012-35957) for financial support. M. T. and A. P. thank MICINN for RyC and JdC contractses_ES
dc.format.extent4 pag.es_ES
dc.format.mimetypeapplication/pdfes_ES
dc.language.isoenges_ES
dc.publisherWiley - V C H Verlag GmbH & Co. KGaAes_ES
dc.relation.ispartofAngewandte Chemiees_ES
dc.rights© 1999 - 2016 John Wiley & Sons, Inces_ES
dc.subject.otherAsymmetric catalysises_ES
dc.subject.otherCyclobutaneses_ES
dc.subject.otherBorones_ES
dc.subject.otherCopperes_ES
dc.titleEnantioselective synthesis of cyclobutylboronates via a copper-catalyzed desymmetrization approaches_ES
dc.typearticlees_ES
dc.subject.ecienciaQuímicaes_ES
dc.date.embargoend2017-06-06
dc.relation.publisherversionhttp://dx.doi.org/10.1002/ange.201601976es_ES
dc.identifier.doi10.1002/ange.201601976es_ES
dc.identifier.publicationfirstpage7083es_ES
dc.identifier.publicationissue24es_ES
dc.identifier.publicationlastpage7086es_ES
dc.identifier.publicationvolume128es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/337776es_ES
dc.relation.projectIDGobierno de España. CTQ2012-35957es_ES
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones_ES
dc.rights.accessRightsopenAccesses_ES
dc.authorUAMTortosa Manzanares, Mariola (264632)
dc.facultadUAMFacultad de Ciencias


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